1: Identification
1.1. Product identifier
Product form : Mixtures
Product name : Ethanol 95/E5
Product code : 64-17-5, 141-78-6
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : For laboratory and manufacturing use only.
1.3. Company Information
REFLECTA LABORATORY SUPPLIES
SECTION 2: Ethanol 95/E5 – Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 3 H226
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Carc. 1A H350
Repr. 2 H361
STOT SE 1 H370
Full text of H statements: see section 16
2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H350 – May cause cancer
(Ingestion)
H361 – Suspected of damaging the unborn child (Ingestion)
H370 – Causes damage to organs (central nervous system, optic nerve) (oral, Dermal)
Precautionary statements (GHS-US) : P201 – Obtain special instructions before use
P202- Do not handle until all safety precautions have been read and understood
P210- Keep away from heat, hot surfaces, open flames, sparks. – No smoking
ETHANOL 95/E5
P233- Keep container tightly closed
P240- Ground/bond container and receiving equipment
P241- Use explosion-proof electrical, lighting, ventilating equipment
P242- Use only non-sparking tools
P243- Take precautionary measures against static discharge
P260- Do not breathe mist, spray, vapors
P264- Wash exposed skin thoroughly after handling
P270- Do not eat, drink or smoke when using this product
P280- Wear eye protection, face protection, protective clothing, protective gloves
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing
P308+P313 – IF exposed or concerned: Get medical advice/attention
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362+P364 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam to
Extinguish
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to comply with local, state and federal regulations
2.3. Other hazards
Other hazards not contributing to the : None.
classification
2.4. Unknown acute toxicity (GHS US)
No data available
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
Full text of H-phrases: see section 16
3.2. Ethanol 95/E5- Mixtures
Ethanol; ethyl alcohol
Contents: 95.00 %W/W
CAS-No. 64-17-5 Index-No. 603-002-00-5 EC-No. 200-578-6 Symbol(s) F R-phrase(s) -R11
Ethyl acetate
Contents: 5.00 %W/W
CAS-No. 141-78-6 Index-No. 607-022-00-5 EC-No. 205-500-4
ETHANOL 95/E5
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general
First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact
First-aid measures after ingestion
: Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with labored breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim’s condition: doctor/hospital. Never give alcohol to drink.
: Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. : Rinse with water. Take victim to a doctor if irritation persists.
: Rinse immediately with plenty of water. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists.
: Rinse mouth with water. Do not induce vomiting. Call Poison Information Centre (www.big.be/antigif.htm). Consult a doctor/medical service if you feel unwell. Ingestion of large quantities: immediately to hospital.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. Respiratory difficulties. Central
nervous system depression. Symptoms similar to those listed under ingestion.
Symptoms/effects after skin contact : Slight irritation.
Symptoms/effects after eye contact : Redness of the eye tissue. Lacrimation. ON CONTINUOUS EXPOSURE/CONTACT: Irritation of the eye tissue.
Symptoms/effects after ingestion : AFTER ABSORPTION OF LARGE QUANTITIES: Risk of aspiration pneumonia. Red skin. Body temperature rise. Damp/clammy skin. Excited/restless. Accelerated heart action. Central
nervous system depression. Dizziness. Narcosis. Headache. Drunkenness. Nausea. Vomiting.
Disturbed motor response. Coordination disorders. Visual disturbances. Impaired
concentration. Delusions. Disturbed sensation of pain. Disturbances of heart rate. Disturbances
of consciousness. Tremor. Cramps/uncontrolled muscular contractions. Dilated pupils.
Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Dry skin. Gastrointestinal complaints. Enlargement/affection of the liver. Change in the haemogramme/blood composition. Cardiac
and blood circulation effects. High arterial pressure. Impairment of the nervous system.
Behavioural disturbances. Mental confusion. Disturbed tactile sensibility. Tremor. Affection
of the bone marrow. Affection of the endocrine system. Weakening of the immune system.
4.3. Indication of any immediate medical attention and special treatment needed
Obtain medical assistance.
SECTION 5: Ethanol 95/E5 – Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Water spray. Alcohol-resistant foam. BC powder. Carbon dioxide. Unsuitable extinguishing media : Solid water jet ineffective as extinguishing medium.
5.2. Special hazards arising from the substance or mixture
Fire hazard : DIRECT FIRE HAZARD. Highly flammable. Gas/vapor flammable with air within explosion limits. INDIRECT FIRE HAZARD. May be ignited by sparks. Gas/vapor spreads at floor level:
ignition hazard. Reactions involving a fire hazard: see “Reactivity Hazard”.
Explosion hazard : DIRECT EXPLOSION HAZARD. Gas/vapour explosive with air within explosion limits. INDIRECT EXPLOSION HAZARD. may be ignited by sparks. Reactions with explosion
hazards: see “Reactivity Hazard”.
Reactivity : Upon combustion: CO and CO2 are formed. Reacts violently with many compounds e.g.: with (strong) oxidizers: (increased) risk of fire/explosion. Violent to explosive reaction with (some)
acids.
5.3. Advice for firefighters
Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to heat.
Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus.
ETHANOL 95/E5
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing. Large spills/in enclosed spaces: compressed air apparatus. See “Material-Handling” to select protective clothing.
Emergency procedures : Keep upwind. Mark the danger area. Consider evacuation. Seal off low-lying areas. Close doors and windows of adjacent premises. Stop engines and no smoking. No naked flames or
sparks. Spark- and explosion-proof appliances and lighting equipment. Keep containers closed.
Wash contaminated clothes.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection. Avoid breathing mist, spray. Emergency procedures : Ventilate area.
6.2. Ethanol 95 – Environmental precautions
Prevent spreading in sewers.
6.3. Methods and material for containment and cleaning up
For containment : Contain released substance, pump into suitable containers. Consult “Material-handling” to select material of containers. Plug the leak, cut off the supply. Dam up the liquid spill. Try to
reduce evaporation. Measure the concentration of the explosive gas-air mixture. Dilute/disperse
combustible gas/vapour with water curtain. Provide equipment/receptacles with earthing. Do
not use compressed air for pumping over spills.
Methods for cleaning up : Take up liquid spill into a non combustible material e.g.: sand, earth, vermiculite or kieselguhr, powdered limestone. Scoop absorbed substance into closing containers. See “Material
handling” for suitable container materials. Carefully collect the spill/leftovers. Damaged/cooled
tanks must be emptied. Do not use compressed air for pumping over spills. Clean
contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent
authority. Wash clothing and equipment after handling.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Ethanol 95 /E5 – Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Comply with the legal requirements. Remove contaminated clothing immediately. Clean contaminated clothing. Handle uncleaned empty containers as full ones. Thoroughly clean/dry
the installation before use. Do not discharge the waste into the drain. Do not use compressed
air for pumping over. Use spark-/explosionproof appliances and lighting system. Take
precautions against electrostatic charges. Keep away from naked flames/heat. Keep away from
ignition sources/sparks. Observe normal hygiene standards. Keep container tightly closed.
Measure the concentration in the air regularly. Work under local exhaust/ventilation.
Hygiene measures : Wash exposed skin thoroughly after handling.
ETHANOL 95/E5
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/…
equipment.
Storage conditions : Keep container tightly closed. Keep only in the original container in a cool, well ventilated place away from : incompatible materials. Keep in fireproof place.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources. ignition sources. Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: oxidizing agents. strong acids. water/moisture. Storage area : Keep out of direct sunlight. Store in a dry area. Ventilation at floor level. Fireproof storeroom. Provide for an automatic sprinkler system. Provide for a tub to collect spills. Provide the tank
with earthing. Meet the legal requirements.
Special rules on packaging : SPECIAL REQUIREMENTS: closing. dry. clean. correctly labelled. meet the legal requirements. Secure fragile packagings in solid containers.
Packaging materials : SUITABLE MATERIAL: stainless steel. aluminium. iron. copper. nickel. synthetic material. glass. MATERIAL TO AVOID: No data available.
7.3. Specific end use(s)
No additional information available
SECTION 8: Ethanol 95 – Exposure controls/personal protection
8.1. Control parameters
Ethyl Alcohol, 95% v/v
| USA ACGIH | ACGIH STEL (ppm) | 1000 ppm (Ethanol; USA; Short time value; TLV – |
| Adopted Value) | ||
| Ethanol (64-17-5) | ||
| USA ACGIH | ACGIH STEL (ppm) | 1000 ppm (Ethanol; USA; Short time value; TLV – |
| Adopted Value) | ||
| USA OSHA | OSHA PEL (TWA) (mg/m³) | 1900 mg/m³ |
| USA OSHA | OSHA PEL (TWA) (ppm) | 1000 ppm |
| Isopropyl Alcohol (2-Propanol) (67-63-0) | ||
| USA ACGIH | ACGIH TWA (ppm) | 200 ppm (2-propanol; USA; Time-weighted average |
| exposure limit 8 h; TLV – Adopted Value) | ||
| USA ACGIH | ACGIH STEL (ppm) | 400 ppm (2-propanol; USA; Short time value; TLV – |
| Adopted Value) | ||
| USA OSHA | OSHA PEL (TWA) (mg/m³) | 980 mg/m³ |
| USA OSHA | OSHA PEL (TWA) (ppm) | 400 ppm |
| Methanol (67-56-1) | |
| USA ACGIH | ACGIH TWA (ppm) |
| USA ACGIH | ACGIH STEL (ppm) |
| USA OSHA | OSHA PEL (TWA) (mg/m³) |
| USA OSHA | OSHA PEL (TWA) (ppm) |
200 ppm (Methanol; USA; Time-weighted average exposure limit 8 h; TLV – Adopted Value) 250 ppm (Methanol; USA; Short time value; TLV – Adopted Value)
260 mg/m³
200 ppm
ETHANOL 95/E5
| 8.2. | Exposure controls |
| Appropriate engineering controls | : Emergency eye wash fountains and safety showers should be available in the immediate |
| vicinity of any potential exposure. Ensure adequate ventilation. | |
| Personal protective equipment | : Safety glasses. Gloves. Protective clothing. |
Materials for protective clothing : GIVE EXCELLENT RESISTANCE: butyl rubber. viton. GIVE GOOD RESISTANCE: neoprene. tetrafluoroethylene. GIVE LESS RESISTANCE: nitrile rubber. polyethylene. GIVE POOR
RESISTANCE: natural rubber. PVA. PVC.
Hand protection : Gloves.
Eye protection : Safety glasses.
Skin and body protection : Protective clothing.
Respiratory protection : Wear gas mask with filter type A if conc. in air > exposure limit.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Liquid.
Molecular mass : 46.07 g/mol
Color : Colourless.
Odor : Alcohol odour. Pleasant odour.
Odor threshold : 100 ppm
188 mg/m³
pH : No data available
Relative evaporation rate (butyl acetate=1) : 2.4
Relative evaporation rate (ether=1) : 8.3
Melting point : -115 °C
Freezing point : No data available
Boiling point : 78 °C
Flash point : 25 °C
Critical temperature : 243 °C
Auto-ignition temperature : 363 °C
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : 59 hPa (20 °C)
Vapor pressure at 50 °C : 300 hPa (50 °C)
Critical pressure : 63840 hPa
Relative vapor density at 20 °C : 1.6
Relative density : No data available
Relative density of saturated gas/air mixture : 1.04
Specific gravity / density : 0.8 g/l
ETHANOL 95/E5
Solubility : Soluble in water. Soluble in ether. Soluble in acetone. Soluble in chloroform. Soluble in oils/fats. Soluble in methanol. Soluble in acids.
Water: Complete
Ethanol: Not applicable
Ether: Complete
Acetone: Complete
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : 0.0012 Pa.s (20 °C)
Explosive properties : No data available
Oxidizing properties : No data available
Explosion limits : 3.3 – 19.0 vol %
67 – 290 g/m³
9.2. Other information
Specific conductivity : 130000 pS/m
Saturation concentration : 112 g/m³
VOC content : 100 %
Other properties : Gas/vapour heavier than air at 20°C. Clear. Hygroscopic. Volatile. Substance has neutral reaction.
SECTION 10: Stability and reactivity
10.1. Reactivity
Upon combustion: CO and CO2 are formed. Reacts violently with many compounds e.g.: with (strong) oxidizers: (increased) risk of fire/explosion. Violent to explosive reaction with (some) acids.
10.2. Chemical stability
Hygroscopic.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
ETHANOL 95/E5
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
| Ethanol (64-17-5) | |
| LD50 oral rat | 10740 mg/kg (Rat; Experimental value,Rat; Experimental value) |
LD50 dermal rabbit > 16000 mg/kg (Rabbit; Literature study)
| Isopropyl Alcohol (2-Propanol) (67-63-0) | |
| LD50 dermal rabbit | 12870 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; 16.4; Rabbit) |
LC50 inhalation rat (mg/l) 73 mg/l/4h (Rat)
| Water (7732-18-5) |
LD50 oral rat ≥ 90000 mg/kg
| Methanol (67-56-1) | |
| LD50 oral rat | > 5000 mg/kg (Rat; BASF test; Literature study; 1187-2769 mg/kg bodyweight; Rat; Weight of evidence) |
| LD50 dermal rabbit | 15800 mg/kg (Rabbit; Literature study) |
| LC50 inhalation rat (mg/l) | 85 mg/l/4h (Rat; Literature study) |
| LC50 inhalation rat (ppm) | 64000 ppm/4h (Rat; Literature study) |
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Based on available data, the classification criteria are not met
Carcinogenicity : May cause cancer (Ingestion).
| Ethyl Alcohol, 95% v/v |
| IARC group |
| Ethanol (64-17-5) |
| IARC group |
| Isopropyl Alcohol (2-Propanol) (67-63-0) |
| IARC group |
1 – Carcinogenic to humans 1 – Carcinogenic to humans 3 – Not classifiable
ETHANOL 95/E5
Reproductive toxicity : Suspected of damaging the unborn child (Ingestion).
Based on available data, the classification criteria are not met
Specific target organ toxicity – single exposure : Causes damage to organs (central nervous system, optic nerve) (oral, Dermal).
Specific target organ toxicity – repeated : Not classified
exposure Based on available data, the classification criteria are not met
Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and : Harmful if swallowed. Based on available data, the classification criteria are not met. symptoms
Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. Respiratory difficulties. Central
nervous system depression. Symptoms similar to those listed under ingestion.
Symptoms/effects after skin contact : Slight irritation.
Symptoms/effects after eye contact : Redness of the eye tissue. Lacrimation. ON CONTINUOUS EXPOSURE/CONTACT: Irritation of the eye tissue.
Symptoms/effects after ingestion : AFTER ABSORPTION OF LARGE QUANTITIES: Risk of aspiration pneumonia. Red skin. Body temperature rise. Damp/clammy skin. Excited/restless. Accelerated heart action. Central
nervous system depression. Dizziness. Narcosis. Headache. Drunkenness. Nausea. Vomiting.
Disturbed motor response. Coordination disorders. Visual disturbances. Impaired
concentration. Delusions. Disturbed sensation of pain. Disturbances of heart rate. Disturbances
of consciousness. Tremor. Cramps/uncontrolled muscular contractions. Dilated pupils.
Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Dry skin. Gastrointestinal complaints. Enlargement/affection of the liver. Change in the haemogramme/blood composition. Cardiac
and blood circulation effects. High arterial pressure. Impairment of the nervous system.
Behavioural disturbances. Mental confusion. Disturbed tactile sensibility. Tremor. Affection of
the bone marrow. Affection of the endocrine system. Weakening of the immune system.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – water : Not harmful to fishes (LC50(96h) >1000 mg/l). Not harmful to invertebrates (Daphnia). Slightly harmful to algae (EC50 (72h): 100 – 1000 mg/l). Harmful to plankton. Not harmful to bacteria
(EC50 >1000 mg/l). No inhibition of activated sludge.
| Ethanol (64-17-5) |
LC50 fish 1 14200 mg/l (LC50; US EPA; 96 h; Pimephales promelas; Flow-through system; Fresh water; Experimental value)
| Isopropyl Alcohol (2-Propanol) (67-63-0) | |
| LC50 fish 2 | 9640 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Flow through system; Fresh water; Experimental value) |
| EC50 Daphnia 2 | 13299 mg/l (EC50; Other; 48 h; Daphnia magna) |
Threshold limit algae 1 > 1000 mg/l (EC50; UBA; 72 h; Scenedesmus subspicatus)
| Methanol (67-56-1) | |
| LC50 fish 1 | 15400 mg/l (LC50; EPA 660/3 – 75/009; 96 h; Lepomis macrochirus; Flow-through system; Fresh water; Experimental value) |
| EC50 Daphnia 1 | > 10000 mg/l (EC50; DIN 38412-11; 48 h; Daphnia magna; Static system; Fresh water; Experimental value) |
| Methanol (67-56-1) | |
| LC50 fish 2 | 10800 mg/l (LC50; 96 h; Salmo gairdneri) |
12.2. Persistence and degradability
| Ethyl Alcohol, 95% v/v |
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Highly mobile in soil.
| Ethanol (64-17-5) | |
| Persistence and degradability | Readily biodegradable in water. Biodegradable in the soil. Highly mobile in soil. |
| Biochemical oxygen demand (BOD) | 0.8 – 0.967 g O ₂/g substance |
| Chemical oxygen demand (COD) | 1.7 g O ₂/gtancesubs |
| ThOD | 2.1 g O ₂/g substance |
ETHANOL 95/E5
BOD (% of ThOD) 0.43
| Isopropyl Alcohol (2-Propanol) (67-63-0) | |
| Persistence and degradability | Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under anaerobic conditions. No test data on mobility of the substance available. |
| Biochemical oxygen demand (BOD) | 1.19 g O ₂/g substance |
| Chemical oxygen demand (COD) | 2.23 g O ₂/g substance |
ThOD 2.4 g O ₂/g substance
| Water (7732-18-5) |
Persistence and degradability Not established.
| Methanol (67-56-1) | |
| Persistence and degradability | Readily biodegradable in water. Biodegradable in the soil. Highly mobile in soil. |
| Biochemical oxygen demand (BOD) | 0.6 – 1.12 g O ₂/g substance |
| Chemical oxygen demand (COD) | 1.42 g O ₂/g substance |
| ThOD | 1.5 g O ce₂/g substan |
| BOD (% of ThOD) | 0.8 (Literature study) |
12.3. Bioaccumulative potential
| Ethyl Alcohol, 95% v/v |
BCF fish 1 1 (BCF; Other; 72 h; Cyprinus carpio; Static system; Fresh water; Read-across)
| Ethanol (64-17-5) | |
| BCF fish 1 | 1 (BCF; Other; 72 h; Cyprinus carpio; Static system; Fresh water; Read-across) |
| Log Pow | -0.31 (Experimental value) |
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
| Isopropyl Alcohol (2-Propanol) (67-63-0) | |
| Log Pow | 0.05 (Weight of evidence approach; Other; 25 °C) |
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
| Water (7732-18-5) |
Bioaccumulative potential Not established.
| Methanol (67-56-1) | |
| BCF fish 1 | < 10 (BCF; 72 h; Leuciscus idus) |
| Log Pow | -0.77 (Experimental value; Other) |
| Bioaccumulative potential | Low potential for bioaccumulation (BCF < 500). |
12.4. Mobility in soil
| Ethyl Alcohol, 95% v/v |
Log Koc Koc,PCKOCWIN v1.66; 1; Read-across
| Ethanol (64-17-5) | |
| Surface tension | 0.022 N/m (20 °C) |
Log Koc Koc,PCKOCWIN v1.66; 1; Read-across
| Isopropyl Alcohol (2-Propanol) (67-63-0) |
Surface tension 0.021 N/m (25 °C)
| Methanol (67-56-1) | |
| Surface tension | 0.023 N/m (20 °C) |
ETHANOL 95/E5
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed
together if this may entail a risk of pollution or create problems for the further management of
the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or
handle hazardous waste shall take the necessary measures to prevent risks of pollution or
damage to people or animals. Recycle by distillation. Remove to an authorized waste
incinerator for solvents with energy recovery. Do not discharge into surface water. May be
discharged to wastewater treatment installation.
Additional information : LWCA (the Netherlands): KGA category 03. Hazardous waste according to Directive 2008/98/EC.
Ecology – waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT
Transport document description : UN1987 Alcohols, n.o.s., 3, II
UN-No.(DOT) : 1987
DOT NA no. : UN1987
Proper Shipping Name (DOT) : Alcohols, n.o.s.
Transport hazard class(es) (DOT) : 3 – Class 3 – Flammable and combustible liquid 49 CFR 173.120 Hazard labels (DOT) : 3 – Flammable liquid
Packing group (DOT) : II – Medium Danger
DOT Special Provisions (49 CFR 172.102) : 172 – This entry includes alcohol mixtures containing up to 5% petroleum products. IB2 – Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T7 – 4 178.274(d)(2) Normal…………. 178.275(d)(3)
TP1 – The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr – tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
TP8 – A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
TP28 – A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used
provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous
material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the
MAWP.
DOT Packaging Exceptions (49 CFR 173.xxx) : 4b;150
DOT Packaging Non Bulk (49 CFR 173.xxx) : 202
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Quantity Limitations Passenger aircraft/rail : 5 L
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 : 60 L
CFR 175.75)
DOT Vessel Stowage Location : B – (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Additional information
Other information : No supplementary information available.
ETHANOL 95/E5
ADR
Transport document d
